The links between CFCs Essay Example for Free

The links between CFCs EssayThere live been many methods to try and investigate the alchemy of the atmosphere. Some scientists use monitoring to find out what is move over in the atmosphere and in what concentration. Many of the substances present have characteristic absoroptions in the infra-red and ultra-violet reigons of the spectrum. (1) Eg Ozone absorbss ultra-violet radiation with wavelengths to a lower place 360nm. (1) Ozone concentration has to be measured over a period of time, at different heights and lattitudes to assimilate sure that any decreases argon not from natural influences. This can be done from the ground, high-altitude planes and satellites. Laboratory measurements be used to determine how substances will behave in the stratosphere like how they are affected by solar radiation and the rates of reaction. The rate constants are truly important and allows the rate to be calculated for intimately any conditions. It is not enough to know how they react in the laboratory because, on this small scale, gases ripple quickly by diffusion (1) but in the stratosphere there are more than larger distances and cognize gasses are not perfectly mixed.We would not be able to make full use of these measurements without fellowship of demeanor movements (meteorology). CFCs in the troposphere are extremely unreactive but in the stratosphere there are much higher levels levels of radiation energy which are needed to break down C-Cl bonds. This energy does not go on the troposphere because it is filtered out by the O2 and O3 molecules present in the stratosphere. Small concentrations of CFC 11 (CCl3F) were discovered in rustic areas, wel away from any sources,and showed that it was able to diffuse to polara.Such a stable gas would accumulate in the atmosphere. Scientists flew into the ozone hole and measured the concentrations of ClO nucleotides and O3. Figure 4 below (1) shows that the concentration of O3 fell dramatically at the floor where the concentration of ClO radicals soared. This was conclusive proof that a catalytic cycle involving Cl radicals must be gnarled in O3 depletion. Also figure 1 (4) shows a severe depletion in the ozone layer over the Antarctic on October 1, 1999.The rapid depletion of CFCs in the stratosphere is due to the high levels of ultra-violet radiation which top outs to the photodissociation of CFC molecules. Eg A CFC 11 molecule would absorb the high energy ultra-violet radiation and fragment to release chlorine radicals CCl3F == CCl2F + Cl. (1) The Cl radical could then destroy ozone in a catlytic cycle (1) Cl + O3 == ClO + O2 ClO + O == Cl + O2 overall O + O3 == 2O2 (1) The chlorine atoms are not used up in these reactions, they are homogeneous catalysts.(4) The raction rate is riotous and one chlorine molecule could destroy thousands of ozone molecules. The oxygen free radicals, O in the second equation, are formed continuosly in the stratosphere. Ozone depletion is most severe over Antartica in the southern spring because of unique live conditions, the sun disappears for six months. In the winter a vortex of cold air isolates the circulating air mass from the rest of the atmosphere (1), polar stratospheric clouds form allowing particles nitric acid frozen around the nuclei of sulfuric acid.The clouds provide a surface for the reaction of HCl with ClONO2. This reaction produces Cl2 which breaks down to form Cl radicals when the sun returns. These radicals lead to the destruction of Ozone. Figure 5 below (1) shows how polar stratospheric clouds help Cl radicals to destroy ozone. As the chemistry of chlorine in the sratosphere is better understood it is shown that some gasses like NO2 and CH4 can react with ClO radicals and interrupt the catalytic cycle Cl + CH4== HCl + CH3 ClO + NO2 == ClONO2 The chlorine atoms become bound up in the stable reservoir molcules, HCl and CIONO2.They endure chemically inactive until realeased (3). CFCs have been used so widely f or many reasons. It has the essential physical properties for a refigerent, appropriate boiling and freezing points (low enough to evapourate efficiently but high enough to liquefy by compression) (2). Its chemically stable, non toxic and cheap. (2) CFCs and the related HCFCs quickly became the refrigerantschioce for almost all applications. It had a wide range of uses, go steady table 2 below(2), and it was better than all previous refigerants. Table 2 (2).Compound Number Bp/ C Major Applications CCl3F CFC11 23 Air conditioners, water chillers, aerosols, coolant CCl2F2 CFC12 -29 Domestic fridges and freezers, car air condtioning, poly(styene) foams Scientists want to use HFCs (hydrofluorocarbons) as a replacement for CFCs because they contain fluorine as the only halogen (2). They similarly do far little damage to stratospheric ozone because HFCs are broken down in the troposphere by OH radicals so very little reaches the stratosphere also the C-F bond is not broken in the strat osphere.HFCs have no effect on O3 but they collapse to global warming. Also existing equipment will have to be modified or redesigned which could be very expensive.References- 1. Article 1 Do CFCs destroy the ozone layer? , taken from ChemistryReview, March 1993. 2. Article 2 The climb on and fall of CFCs, taken from Chemistry Review, September 1996. 3. Chemical Ideas pg 242 Heinemann 4. http//www. cis. ohio-state. edu/hypertxt/faq/usenet/ozone-depletion/top. html.